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Webof bridgehead cations (5)-(7) which possess surprisingly high thermodynamic stability. One of the interesting observations that emerged from our study of the bicyclo[l.l.l]pentyl bromides3 was the deviant behaviour exhibited by the parent (2) which ionized at a faster rate than that predicted by the Ham- WebMeaning of bridgehead in English. bridgehead. noun [ C ] uk / ˈbrɪdʒ.hed / us / ˈbrɪdʒ.hed /. a good position that an army has taken in enemy land, from which it can attack the … WebTools. In organic chemistry, Bredt's rule is an empirical observation that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed it in 1902 [1] and codified it in 1924. [2] It primarily relates to bridgeheads with carbon ... rifat bashir